As Jard said, one of the keys is to start the morning with some boots that are totally dry. If you can use the boot dryers, they are worth every penny and are not that expensive. If you are at a hunting camp without electricity, they make one that runs on propane, but may be more of a pain to use.
I have gone to a two boot system that has worked well for me. I have two pairs of the Muck Woody Max. One pair is my normal boot size, and the other is a full size larger. I use the larger size in the morning when it is coldest. It is amazing how much difference having the extra space means for warmth. A lot of folks really defeat themselves by wearing extra pairs of socks and having a really tight fit. I use the smaller pair in the evenings. By switching out between morning and evening hunts, both pairs seem to dry out before I need them again. With an all day sit in the larger pair, I usually use a boot dryer at night. All I use are a thick pair of merino wool socks.
I'm good down to about 25 deg. in the Woody Max. Below that, I reach for a pair of boots with at least 1200 gr. of thinsulate. Bass Pro sells one that I got on sale that is a pac boot with the thinsulate booty separate from the boot. That gives you the ability to take it out to dry at night. I'm good down into the single digits with those. Below that, I grab a pair of boot blankets to go with the pac boots.
As an aside to the warmth deal, I have seen a major difference in deer response since I have quit wearing my hunting boots in the truck. I wash them down in the no-scent soap, and store them where the soles never touch a truck floor mat. I wear some little Sportsman Guide neoprene slip ons for the drive to the hunting site, and put on my hunting boots outside of the truck. It has made a major difference on how deer react when they cross my path where I walk into the stand.
